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薄膜润滑 5

Cu(In 4

Ga)Se2 3

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CCS 1

CO2分离 1

Ga)Se2光伏组件 1

HSLC钢 1

Ni–Ti–Cu–V合金 1

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交互式图像分割；多元自适应回归样条；集成学习；薄板样条回归；半监督学习；支持向量回归 1

交错缠绕 1

低温 1

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Diffusive gradients in thin films using molecularly imprinted polymer binding gels for in situ measurements

Ying Cui, Feng Tan, Yan Wang, Suyu Ren, Jingwen Chen

《环境科学与工程前沿（英文）》 2020年 第14卷 第6期 doi: 10.1007/s11783-020-1290-5

摘要： Abstract • Selective molecularly imprinted polymer (MIP) binding gel was prepared. • MIP-DGT showed excellent uptake performance for antibiotics. • In situ measurement of antibiotics in wastewaters via MIP-DGT was developed. • The MIP-DGT method was robust, reliable, and highly sensitive. Urban wastewater is one of main sources for the introduction of antibiotics into the environment. Monitoring the concentrations of antibiotics in wastewater is necessary for estimating the amount of antibiotics discharged into the environment through urban wastewater treatment systems. In this study, we report a novel diffusive gradient in thin films (DGT) method based on molecularly imprinted polymers (MIPs) for in situ measurement of two typical antibiotics, fluoroquinolones (FQs) and sulfonamides (SAs) in urban wastewater. MIPs show specific adsorption toward their templates and their structural analogs, resulting in the selective uptake of the two target antibiotics during MIP-DGT deployment. The uptake performance of the MIP-DGTs was evaluated in the laboratory and was relatively independent of solution pH (4.0–9.0), ionic strength (1–750 mmol/L), and dissolved organic matter (DOM, 0–20 mg/L). MIP-DGT samplers were tested in the effluent of an urban wastewater treatment plant for field trials, where three SA (sulfamethoxazole, sulfapyridine, and trimethoprim) and one FQ (ofloxacin) antibiotics were detected, with concentrations ranging from 25.50 to 117.58 ng/L, which are consistent with the results measured by grab sampling. The total removal efficiency of the antibiotics was 80.1% by the treatment plant. This study demonstrates that MIP-DGT is an effective tool for in situ monitoring of trace antibiotics in complex urban wastewaters.

关键词： Diffusive gradients in thin films     Molecularly imprinted polymers     Selective uptake     Antibiotics     Passive sampling    

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Where physics meets chemistry: Thin film deposition from reactive plasmas

Andrew Michelmore, Jason D. Whittle, James W. Bradley, Robert D. Short

《化学科学与工程前沿（英文）》 2016年 第10卷 第4期   页码 441-458 doi: 10.1007/s11705-016-1598-7

摘要： Functionalising surfaces using polymeric thin films is an industrially important field. One technique for achieving nanoscale, controlled surface functionalization is plasma deposition. Plasma deposition has advantages over other surface engineering processes, including that it is solvent free, substrate and geometry independent, and the surface properties of the film can be designed by judicious choice of precursor and plasma conditions. Despite the utility of this method, the mechanisms of plasma polymer growth are generally unknown, and are usually described by chemical (i.e., radical) pathways. In this review, we aim to show that plasma physics drives the chemistry of the plasma phase, and surface-plasma interactions. For example, we show that ionic species can react in the plasma to form larger ions, and also arrive at surfaces with energies greater than 1000 kJ?mol (>10 eV) and thus facilitate surface reactions that have not been taken into account previously. Thus, improving thin film deposition processes requires an understanding of both physical and chemical processes in plasma.

关键词： thin films     plasma physics     plasma chemistry     functionalization     polymer    

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Design and analysis of Salisbury screens and Jaumann absorbers for solar radiation absorption

Xing FANG, C. Y. ZHAO, Hua BAO

《能源前沿（英文）》 2018年 第12卷 第1期   页码 158-168 doi: 10.1007/s11708-018-0542-6

摘要： Two types of resonance absorbers, i.e., Salisbury screens and Jaumann absorbers are systematically investigated in solar radiation absorption. Salisbury screen is a metal-dielectric-metal structure which overcomes the drawback of bulky thickness for solar spectrum. Such structures have a good spectral selective absorption property, which is also insensitive to incident angles and polarizations. To further broaden absorption bandwidth, more metal and dielectric films are taken in the structure to form Jaumann absorbers. To design optimized structural parameters, the admittance matching equations have been derived in this paper to give good initial structures, which are valuable for the following optimization. Moreover, the analysis of admittance loci has been conducted to directly show the effect of each layer on the spectral absorptivity, and then the effect of thin films is well understood. Since the fabrication of these layered absorbers is much easier than that of other nanostructured absorbers, Salisbury screen and Jaumann absorbers have a great potential in large-area applications.

关键词： thin films     admittance loci     solar absorber    

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碱金属掺杂对CIGS 薄膜及电池器件的影响

孙云,林舒平,李伟,程世清,张运祥,刘一鸣,刘玮

《工程（英文）》 2017年 第3卷 第4期   页码 452-459 doi: 10.1016/J.ENG.2017.04.020

摘要：

本文总结了Cu(In, Ga)Se2 (CIGS) 电池中掺杂碱金属的发展历史和一些重要成果，综述了碱金属掺杂方式对CIGS 吸收层及器件性能的影响。通过分析由(NaF+KF)-PDT 导致的CIGS 表面结构及电学性能的改变，我们提出并解释了如下几个问题：①在低温沉积CIGS 薄膜过程中，Na 促进了CuInSe2的优先形成，排挤Ga 向Mo 衬底扩散，造成CIGS 薄膜的分层现象；② Na 原子钝化CIGS 晶界及表面缺陷从而提高空穴载流子浓度的相关机制；③过渡层减薄提高了短路电流（JSC）而不产生开路电压（VOC）损失，这不仅归因于化学浴沉积初期过渡层较好的包覆性，还在于受主缺陷VCu− 转型为施主缺陷CdCu+时密度的增加，强化了同质浅埋结；④ (NaF+KF)-PDT 使CIGS 吸收层表面价带降低，进一步抑制了CIGS 吸收层和过渡层界面的复合，是提高电池开路电压与填充因子的重要原因。

关键词： 碱金属     Cu(In     Ga)Se2     薄膜太阳能电池     PDT    

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Ultrathin microcrystalline hydrogenated Si/Ge alloyed tandem solar cells towards full solar spectrum conversion

Yu Cao, Xinyun Zhu, Xingyu Tong, Jing Zhou, Jian Ni, Jianjun Zhang, Jinbo Pang

《化学科学与工程前沿（英文）》 2020年 第14卷 第6期   页码 997-1005 doi: 10.1007/s11705-019-1906-0

摘要： Thin film solar cells have been proved the next generation photovoltaic devices due to their low cost, less material consumption and easy mass production. Among them, micro-crystalline Si and Ge based thin film solar cells have advantages of high efficiency and ultrathin absorber layers. Yet individual junction devices are limited in photoelectric conversion efficiency because of the restricted solar spectrum range for its specific absorber. In this work, we designed and simulated a multi-junction solar cell with its four sub-cells selectively absorbing the full solar spectrum including the ultraviolet, green, red as well as near infrared range, respectively. By tuning the Ge content, the record efficiency of 24.80% has been realized with the typical quadruple junction structure of a-Si:H/a-Si Ge :H/µc-Si:H/µc-Si Ge :H. To further reduce the material cost, thickness dependent device performances have been conducted. It can be found that the design of total thickness of 4 m is the optimal device design in balancing the thickness and the . While the design of ultrathin quadruple junction device with total thickness of 2 m is the optimized device design regarding cost and long-term stability with a little bit more reduction in . These results indicated that our solar cells combine the advantages of low cost and high stability. Our work may provide a general guidance rule of utilizing the full solar spectrum for developing high efficiency and ultrathin multi-junction solar cells.

关键词： thin films     solar cells     quadruple junction solar cell     amorphous silicon     silicon germanium alloy     quantum efficiency    

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Anthocyanins/chitosan films doped by nano zinc oxide for active and intelligent packaging: comparison

《化学科学与工程前沿（英文）》 2023年 第17卷 第6期   页码 704-715 doi: 10.1007/s11705-022-2270-z

摘要： The multifunctional films was prepared by blending chitosan and nano-ZnO with purple tomato anthocyanins or black wolfberry anthocyanins. The properties of films functioned by anthocyanins source and nano-ZnO content were studied. It was found purple tomato anthocyanins showed more significant color change against pH than black wolfberry anthocyanins. The nano-ZnO were widely dispersed in matrix and enhanced the compatibility of anthocyanins with chitosan. However, the anthocyanins source influenced the properties of the films more slightly than nano-ZnO addition. The tensile strength, antioxidant and antibacterial effects of the chitosan films dramatically increased after cooperated by nano-ZnO and anthocyanins, which also enhanced with increase of nano-ZnO content, whereas the elongation at break of the composite films decreased. Especially, the anthocyanin and nano-ZnO promoted the antibacterial activity of films synergistically. Composite films made from black wolfberry anthocyanins exhibited higher mechanical performance than those made from purple tomato anthocyanins but weaker antibacterial effects. The purple tomato anthocyanins/chitosan and nano-ZnO/purple tomato anthocyanins/chitosan films effectively reflected pork spoilage, changing their colors from dark green to brown, indicating the potential for applications in active and intelligent food packaging.

关键词： bio-based     multifunction     colorimetric indicator     active and intelligent packaging    

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无溶剂气相制备用于可持续分离过程的膜材料 Perspective

赵俊杰, Karen K. Gleason

《工程（英文）》 2020年 第6卷 第12期   页码 1432-1442 doi: 10.1016/j.eng.2020.05.002

摘要：

可用于水净化、碳捕集、生物燃料生产、燃料电池运行以及节能工业分离操作的可持续化工过程亟待发展下一代膜材料。膜的无溶剂制备不仅消除了有机溶剂的潜在环境问题，而且解决了脆弱聚合物基材的膨胀问题。此外，采用无溶剂气相沉积方法可以减少合成微孔材料[如金属有机骨架（MOF）]所需的活化步骤。本文综述了几种真空沉积工艺，包括引发式化学气相沉积（iCVD）、引发式等离子体增强化学气相沉积（iPECVD）、无溶剂气相沉积原位聚合（SLIP）、原子层沉积（ALD） 和分子层沉积（MLD）。这些无溶剂气相沉积方法在制备薄膜复合膜结构中的超薄选择层方面极具优势，而且能够保形地修饰纳米级孔道并精确调节孔径和孔内官能团。所制备的膜在气体分离、 纳滤、海水淡化和水/油分离等方面表现出颇具应用潜力的性能。因此，开发新型膜材料、放大可用于无溶剂气相沉积的高通量反应器将对化学工业产生巨大影响。

关键词： 膜分离     化学气相沉积     原子层沉积     分子层沉积     薄膜     金属有机骨架     聚合物     先进制造    

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Nanostructured gold films exhibiting almost complete absorption of light at visible wavelengths

Hanbin Zheng, Christine Picard, Serge Ravaine

《化学科学与工程前沿（英文）》 2018年 第12卷 第2期   页码 247-251 doi: 10.1007/s11705-018-1710-2

摘要： Nanostructured metal surfaces have been known to exhibit properties that deviate from that of the bulk material. By simply modifying the texture of a metal surface, various unique optical properties can be observed. In this paper, we present a simple two step electrochemical process combining electrodeposition and anodization to generate black gold surfaces. This process is simple, versatile and up-scalable for the production of large surfaces. The black gold films have remarkable optical behavior as they absorb more than 93% of incident light over the entire visible spectrum and also exhibit no specular reflectance. A careful analysis by scanning electron microscopy reveals that these unique optical properties are due to their randomly rough surface, as they consist in a forest of dendritic microstructures with a nanoscale roughness. This new type of black films can be fabricated to a large variety of substrates, turning them to super absorbers with potential applications in photovoltaic solar cells or highly sensitive detectors and so on.

关键词： nanostructuration     light absorption     coating     gold     electrodeposition     anodization    

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Photothermal-Management Agricultural Films toward Industrial Planting: Opportunities and Challenges

Song Zhang,Zhang Chen,Chuanxiang Cao,Yuanyuan Cui,Yanfeng Gao,

《工程（英文）》 doi: 10.1016/j.eng.2023.06.016

摘要： As indispensable parts of greenhouses and plant factories, agricultural covering films play a prominent role in regulating microclimate environments. Polyethylene covering films directly transmit the full solar spectrum. However, this high level of sunlight transmission may be inappropriate or even harmful for crops with specific photothermal requirements. Modern greenhouses are integrated with agricultural covering materials, heating, ventilation, and air conditioning (HVAC) systems, and smart irrigation and communication technologies to maximize planting efficiency. This review provides insight into the photothermal requirements of crops and ways to meet these requirements, including new materials based on passive radiative cooling and light scattering, simulations to evaluate the energy consumption and environmental conditions in a greenhouse, and data mining to identify key biological growth factors and thereby improve new covering films. Finally, future challenges and directions for photothermal-management agricultural films are elaborated on to bridge the gap between lab-scale research and large-scale practical applications.

关键词： Greenhouse     Photothermal management     Passive radiative cooling     Light scattering    

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Fixturing technology and system for thin-walled parts machining: a review

《机械工程前沿（英文）》 2022年 第17卷 第4期 doi: 10.1007/s11465-022-0711-5

摘要： During the overall processing of thin-walled parts (TWPs), the guaranteed capability of the machining process and quality is determined by fixtures. Therefore, reliable fixtures suitable for the structure and machining process of TWP are essential. In this review, the key role of fixtures in the manufacturing system is initially discussed. The main problems in machining and workholding due to the characteristics of TWP are then analyzed in detail. Afterward, the definition of TWP fixtures is reinterpreted from narrow and broad perspectives. Fixture functions corresponding to the issues of machining and workholding are then clearly stated. Fixture categories are classified systematically according to previous research achievements, and the operation mode, functional characteristics, and structure of each fixture are comprehensively described. The function and execution mode of TWP fixtures are then systematically summarized and analyzed, and the functions of various TWP fixtures are evaluated. Some directions for future research on TWP fixtures technology are also proposed. The main purpose of this review is to provide some reference and guidance for scholars to examine TWP fixtures.

关键词： thin-walled part (TWP)     fixture     machining     fixture categories     fixture function    

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影响微电子机械系统成品率和可靠性和粘合力和磨擦力

王渭源

《中国工程科学》 2000年 第2卷 第3期   页码 36-41

摘要：

文章评述了影响微电子机械系统（MEMS)成品率和可靠性的粘合力和摩擦力问题。在用氢氟酸(HF)腐蚀牺牲层、释放多晶Si微结构、干燥时，由于Si片表面薄层水的表面张力使两片亲水、间隙在微米量级的a片粘合起来，称为“释放有关粘合”。粘合也发生在封装后器件中，当输入信号过冲时，由于Si片表面的化学状态将Si片粘合起来，称为“使用中粘合”。解决粘合的最好办法是：在MEMS微结构的表面涂以抗粘合薄膜，将成品器件在干燥气氛下封装。介绍了抗粘合薄膜的制备工艺和目前存在的问题。相比之下，具有高速运动的MEMS,其摩擦力问题更为复杂。应用抗粘合薄膜，解决了粘合，也降低了摩擦力，但摩擦依然存在。摩擦带来磨损，降低器件可靠性和寿命。寻找既抗粘合、又耐磨的薄膜，是解决高速运动MEMS可靠性和寿命的一个关键。

关键词： 微电子机械系统     粘合力     摩擦力     抗粘合薄膜     耐磨损薄膜    

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A measurement system for thin elastohydrodynamic lubrication films

WANG Xuefeng, GUO Feng, YANG Peiran

《机械工程前沿（英文）》 2007年 第2卷 第2期   页码 193-196 doi: 10.1007/s11465-007-0032-8

摘要： An elastohydrodynamic lubrication (EHL) film measurement system using multi-beam interferometry is introduced in this paper. The measurement principle and the instrumentation are discussed. A simple and efficient method is suggested to obtain the fringe order of measured points. It is demonstrated that the presented measurement system can provide continuous measurement of lubricating films from nano to micro scales at a nano-level resolution, and can be used to investigate ultra-thin EHL films and tiny variations in EHL films.

关键词： instrumentation     continuous measurement     elastohydrodynamic lubrication     ultra-thin     measurement    

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Position-varying surface roughness prediction method considering compensated acceleration in milling of thin-walled

《机械工程前沿（英文）》 2021年 第16卷 第4期   页码 855-867 doi: 10.1007/s11465-021-0649-z

摘要： Machined surface roughness will affect parts’ service performance. Thus, predicting it in the machining is important to avoid rejects. Surface roughness will be affected by system position dependent vibration even under constant parameter with certain toolpath processing in the finishing. Aiming at surface roughness prediction in the machining process, this paper proposes a position-varying surface roughness prediction method based on compensated acceleration by using regression analysis. To reduce the stochastic error of measuring the machined surface profile height, the surface area is repeatedly measured three times, and Pauta criterion is adopted to eliminate abnormal points. The actual vibration state at any processing position is obtained through the single-point monitoring acceleration compensation model. Seven acceleration features are extracted, and valley, which has the highest R-square proving the effectiveness of the filtering features, is selected as the input of the prediction model by mutual information coefficients. Finally, by comparing the measured and predicted surface roughness curves, they have the same trends, with the average error of 16.28% and the minimum error of 0.16%. Moreover, the prediction curve matches and agrees well with the actual surface state, which verifies the accuracy and reliability of the model.

关键词： surface roughness prediction     compensated acceleration     milling     thin-walled workpiece    

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Flexible, ultrathin, and multifunctional polypyrrole/cellulose nanofiber composite films with outstanding

《化学科学与工程前沿（英文）》 2023年 第17卷 第8期   页码 1028-1037 doi: 10.1007/s11705-022-2251-2

摘要： Electrodes that combine energy storage with mechanical and photothermal performance are necessary for efficient development and use of flexible energy storage and conversion devices. In this study, the flexible, ultrathin, and multifunctional polypyrrole/cellulose nanofiber composite films were fabricated via a one-step “soak and polymerization” method. The dense sandwich structure and strong interfacial interaction endowed polypyrrole/cellulose nanofiber composite films with excellent flexibility, outstanding mechanical strength, and desired toughness. Interestingly, the polypyrrole/cellulose nanofiber composite film electrodes with quaternary amine functionalized cellulose nanofiber had the highest specific mass capacitance (392.90 F∙g–1) and specific areal capacitance (3.32 F∙cm–2) than the electrodes with unmodified and carboxyl functionalized cellulose nanofibers. Further, the polypyrrole/cellulose nanofiber composite films with sandwich structure had excellent photothermal conversion properties. This study demonstrated a feasible and versatile method for preparing of multifunctional composite films, having promising applications in various energy storage fields.

关键词： cellulose nanofiber     electrochemical     photothermal conversion     polypyrrole    

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Operating characteristic analysis on the ultra-thin low temperature floor-heating system

Hualing ZHANG, Xiaopeng SONG

《结构与土木工程前沿（英文）》 2013年 第7卷 第2期   页码 127-132 doi: 10.1007/s11709-013-0200-3

摘要： Prefabricated ultra-thin radiant heating panel, as a new heating terminal type, is becoming a highlight in Yangtze River Valley area, China recently. However, there is a lack of operating characteristic research in this region, especially the energy consumption and operating mode are even less. To obtain these data, a heating system was set up in a duplex house in Chongqing. The test results show that the floor heating system could almost satisfy thermal comfort requirement at supply water temperature 45°C. But the preheating time was up to 4.5 h which was 1 h longer than that at supply water temperature 50°C. Meanwhile, the energy consumption at supply water temperature 50°C increased 0.10 Nm /h, and the operating efficiency decrease about 2.6% compared to those at water temperature 45°C. Considering both the thermal lag and operating efficiency, a reasonable suggestion was proposed in this paper. That was, the standard families which just stay home at night should adopt the interim mode of partial room with part time. And the supply water temperature should be properly raised during the preheating period and lowered down in the steady heating stage.

关键词： ultra-thin floor heating panel     the preheating time     thermal comfort     energy saving    

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标题 作者 时间 类型 操作

Diffusive gradients in thin films using molecularly imprinted polymer binding gels for in situ measurements

Ying Cui, Feng Tan, Yan Wang, Suyu Ren, Jingwen Chen

期刊论文

Where physics meets chemistry: Thin film deposition from reactive plasmas

Andrew Michelmore, Jason D. Whittle, James W. Bradley, Robert D. Short

期刊论文

Design and analysis of Salisbury screens and Jaumann absorbers for solar radiation absorption

Xing FANG, C. Y. ZHAO, Hua BAO

期刊论文

碱金属掺杂对CIGS 薄膜及电池器件的影响

孙云,林舒平,李伟,程世清,张运祥,刘一鸣,刘玮

期刊论文

Ultrathin microcrystalline hydrogenated Si/Ge alloyed tandem solar cells towards full solar spectrum conversion

Yu Cao, Xinyun Zhu, Xingyu Tong, Jing Zhou, Jian Ni, Jianjun Zhang, Jinbo Pang

期刊论文

Anthocyanins/chitosan films doped by nano zinc oxide for active and intelligent packaging: comparison

期刊论文

无溶剂气相制备用于可持续分离过程的膜材料

赵俊杰, Karen K. Gleason

期刊论文

Nanostructured gold films exhibiting almost complete absorption of light at visible wavelengths

Hanbin Zheng, Christine Picard, Serge Ravaine

期刊论文

Photothermal-Management Agricultural Films toward Industrial Planting: Opportunities and Challenges

Song Zhang,Zhang Chen,Chuanxiang Cao,Yuanyuan Cui,Yanfeng Gao,

期刊论文

Fixturing technology and system for thin-walled parts machining: a review

期刊论文

影响微电子机械系统成品率和可靠性和粘合力和磨擦力

王渭源

期刊论文

A measurement system for thin elastohydrodynamic lubrication films

WANG Xuefeng, GUO Feng, YANG Peiran

期刊论文

Position-varying surface roughness prediction method considering compensated acceleration in milling of thin-walled

期刊论文

Flexible, ultrathin, and multifunctional polypyrrole/cellulose nanofiber composite films with outstanding

期刊论文

Operating characteristic analysis on the ultra-thin low temperature floor-heating system

Hualing ZHANG, Xiaopeng SONG

期刊论文